Structure factor scaling in colloidal phase separation

Structure factor scaling in colloidal phase separation.

The dynamical scaling hypothesis for the structure factor, S (q) , in depletion-driven colloidal phase separation is studied by carrying out Brownian dynamics simulations. A true dynamical scaling is observed for shallow quenches into the two-phase coexistence region. In such a quench, compact clusters nucleate and grow with time and there is only one characteristic length scale in the system a...

Charge renormalization and phase separation in colloidal suspensions

– We explore the effects of counterion condensation on fluid-fluid phase separation in charged colloidal suspensions. It is found that formation of double layers around the colloidal particles stabilizes suspensions against phase separation. Addition of salt, however, produces an instability which, in principle, can lead to a fluid-fluid separation. The instability, however, is so weak that it ...

Adsorption, aggregation and phase separation in colloidal systems

Structure and dynamics of a phase-separating active colloidal fluid.

We examine a minimal model for an active colloidal fluid in the form of self-propelled Brownian spheres that interact purely through excluded volume with no aligning interaction. Using simulations and analytic modeling, we quantify the phase diagram and separation kinetics. We show that this nonequilibrium active system undergoes an analog of an equilibrium continuous phase transition, with a b...

Phase behavior and structure of colloidal bowl-shaped particles: simulations.

We study the phase behavior of bowl-shaped particles using computer simulations. These particles were found experimentally to form a metastable wormlike fluid phase in which the bowl-shaped particles have a strong tendency to stack on top of each other [M. Marechal, Nano Lett. 10, 1907 (2010)]. In this work, we show that the transition from the low-density fluid to the wormlike phase has an int...